PFAS shows up in Haw River, Pittsboro water, but little local outcry

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By Greg Barnes

On a windblown day in March, Emily Sutton wore rubber wading boots as she stood on the muddy banks of the Haw River and dipped a plastic sample bottle into the chilly, rushing water.

a woman in rubber boots collects water from a muddy river, looking for PFAS. She's wearing a sweater, winter clothes
Emily Sutton, the Haw River riverkeeper, takes samples in the Haw River in March. A sample she took in July 2018 near Pittsboro drinking water intake measured 1,076 parts per trillion of PFAS, the highest recorded in the state. Photo credit: Greg Barnes

Sutton, the Haw River riverkeeper, started her morning testing for at the former mill town of Saxapahaw. Slowly, she wound her way downstream to Pittsboro in her hybrid Toyota Highlander, drawing samples in several stretches of the river along the way.

Sutton had been taking the samples monthly since at least July 2018. That’s the month her samples revealed seven types of PFAS with total concentrations of 1,076 parts per trillion in the river near the old textile community of Bynum, where Pittsboro draws its drinking water.

The concentrations were the highest detected in any North Carolina river since researchers found GenX and a stew of other PFAS compounds dozens of miles away in the Cape Fear River below the Chemours Fayetteville Works chemical plant.

That discovery led to a story in the Wilmington Star-News in June 2017, resulting in an explosion of citizen outcry, the formation of activist groups and the filing of scores of lawsuits against Chemours.

The chemical company eventually entered a consent order with the state, agreeing in February of this year to pay $12 million in fines and to keep GenX out of the river, air and groundwater.

It’s been a far different story in Pittsboro, where researchers have identified and documented contamination in the town’s drinking water for decades, but there’s been little done about it and almost no outcry.

Among the first documented studies came in 1985, when an investigation by the Haw River Assembly concluded that “the drinking water in Pittsboro was contaminated by industrial pollutants from cities upriver, including Greensboro, Reidsville and Burlington.”

Study after study

Twenty-two years after that study, a research team led by Mark Stryner of the U.S. Environmental Protection Agency found high levels of PFAS contamination throughout much of the Cape Fear River basin, from Greensboro to just downriver of the Chemours chemical plant in Bladen County.

According to that report, the highest level of PFAS — 942 parts per trillion — was found in the Haw River near where Pittsboro draws its drinking water.

The researchers published their findings in 2007 in Environmental Science Technology, along with a prophetic warning.

“In general,” the report concluded, “the indication of a wide variety of PFC (perfluorinated compound) sources indicates that much further work will be required to evaluate this river system and the potential impacts on drinking water sources, wildlife species, and potential human exposures.

“This study contributes to the growing body of data that suggests that PFC contamination in the waterways of the industrialized world is pervasive and as yet poorly characterized.”

‘It just hasn’t captured the public’

In 2013, another group of researchers, this time led by Detlef Knappe of N.C. State University, returned to the Haw River to conduct more tests.

Knappe’s group had set out to look for bromide, a compound that reacts with drinking water disinfectants to produce toxic byproducts, including trihalomethanes, which can contribute to cancer. They found not only an abundance of bromide, but also high levels of PFAS and 1,4 dioxane, an industrial solvent that the EPA also lists as a probable carcinogen.

To lower sample bottles from the old Bynum bridge, NC State graduate students Catalina Lopez and Zachary Hopkins use a plastic cord dispenser, a long rope, and PVC pipe drilled with holes so it can sink to get a sample bottle into the Haw River and back up again. Photo by Julie Williams Dixon, taken during 2016 water collecting event.

In Pittsboro, the research team found the two legacy PFAS compounds — known as PFOA and PFOS — at concentrations exceeding 70 parts per trillion, the level the EPA now considers safe for a lifetime of consumption. Levels exceeding the threshold were found on 57 of 127 sampling days, according to N.C. State University.

Despite all of the studies, the public outcry that began after Knappe’s team of scientists found GenX in Wilmington’s drinking water has not materialized in Pittsboro.

Knappe said he has long wondered why.

“The information is out there but maybe it just hasn’t captured the public in the same way as it has with the GenX issue,” Knappe said. “There is no clear bad actor. With GenX, it was clear.”

Yet another study to focus on Pittsboro could change that.

This latest one, led by Duke University researchers Heather Stapleton and Lee Ferguson, aims, in part, to determine the sources of the contamination and the health effects it may be having on Pittsboro’s residents.

The study was made possible by a $495,000 grant from Duke, Stapleton said. It officially began July 1 and is expected to take three years to complete.

Positive samples from Jordan Lake

In 2017, Stapleton, a professor at Duke’s Nicholas School of the Environment, began a study looking at the high rate of kidney disease in Robeson County.

Stapleton wondered whether the water in Robeson County was making people sick, so she decided to have it tested. She also decided to have her own tap water tested, to use a control for the study.

To Stapleton’s surprise, the test results for her tap water came back high in PFAS, leading her to spend about $400 on a reverse osmosis filtration system for her Cary home. It also led her on a quest to find out where the contamination was coming from.

It didn’t take long before samples taken in Jordan Lake came back positive for certain types of PFAS. Stapleton thinks much of the contamination is coming from the Haw River.

Since its discovery in the lake, Durham, Raleigh, Cary, Apex, Chapel Hill, Carrboro and other communities in the Triangle have found PFAS in their drinking water.

But nowhere are the levels as high as they are in Pittsboro, where concentrations during an October 2018 test revealed five different PFAS measuring a combined 270.8 parts per trillion in finished drinking water. (Subsequent monthly testing through Feb. 16 revealed much lower numbers. The state experienced high rainfall those months.)

A report prepared by Stapleton and other researchers seeking the grant from Duke  says the “levels in Pittsboro are particularly elevated compared to other cities,” noting that they are “30 times greater than those in Durham.”

The report also said, “PFAS levels in Pittsboro are similar to the GenX levels measured along the Cape Fear River basin.”

Human studies to start

The discovery of PFAS in the tap water at Stapleton’s Cary home and in Jordan Lake came the year before the legislature approved $5 million for the N.C. Policy Collaboratory’s PFAST Network to study contamination across the state.

The collaboratory-funded team — made up of researchers from seven universities in the state — is now testing surface waters and municipal drinking water across North Carolina for PFAS. It is also testing food and wildlife for the contamination and is conducting many other related studies, including the ability of in-home filters to remove PFAS from tap water in Pittsboro, Durham, Raleigh, Cary, Apex and Chapel Hill.

But no funding was included to evaluate the impact of PFAS exposure on human health, evaluate sources and water-use policies in the Triangle area and to study ways to limit PFAS exposure, according to the report that sought the grant from Duke.

Now that the grant has been approved, Stapleton said, Duke researchers plan to recruit about 30 Pittsboro residents to provide blood and drinking water samples, which will be analyzed for PFAS.

Scroll to the page bottom to read Stapleton’s proposal.

“These measurements will allow us to model the body burdens of PFAS in residents receiving Pittsboro drinking water,” the grant request says.

Among many other health conditions, exposure to high levels of PFAS has been linked to premature birth and low birth weight, which can cause chronic health conditions, including respiratory and metabolic disorders, the study says.

In a July 18 article by Harvard’s T.H. Chan School of Public Health, it was suggested that the EPA’s health advisory for PFOA should be lowered to 0.1 parts per trillion, or 700 times lower than the current advisory. Researchers found that pancreatic tumors formed in rodents even with very low doses of PFOA.

Frustrated by the EPA’s inaction, some states, including California, Minnesota, Michigan, Vermont, New York and New Jersey, have reduced or are considering substantial reductions in health advisories for PFAS substances.

Contamination source unknown

Another aspect of the Duke study will be to predict PFAS levels in drinking water in Pittsboro, Cary and Apex.

Researchers know that much of the PFAS in the Haw River is coming from wastewater treatment plant effluents and stormwater runoff from fields, where sewage sludge is applied to land.

But they don’t know who is producing the contamination.

Many industries discharge their waste directly into sewer systems that flow into the treatment plants, making it extremely difficult to pinpoint the sources.

To combat the problem, the state Department of Environmental Quality has ordered 25 municipalities in the Cape Fear River Basin to begin monthly monitoring for PFAS and 1,4 dioxane. Monitoring began July 1.

The purpose is to identify which wastewater treatment plants are receiving PFAS and to work with the municipalities to reduce the contamination at its source.

Researchers and state regulators have another problem to deal with this time of year. They suspect that concentrations of PFAS in the Haw River increase during periods of hot, dry weather, when the river is at its lowest flow. More testing is needed to be sure, they say.

“We are really worried that if we go into another bad drought it could go much higher,” Stapleton said. “The Haw River seems very vulnerable to the flow and drought.”

The researchers believe that is one reason the sample taken by Sutton in July of last year measured more than 1,000 parts per trillion for PFAS near Pittsboro’s water intake.

The levels are down considerably since then, though. Stapleton said a sample taken in June near Pittsboro’s water intake found PFAS at 50 parts per trillion, nearly 20 times lower than Sutton’s sample. The combined levels of PFOA and PFOS measured 17 parts per trillion at the same site, Stapleton said.

But that doesn’t mean the levels won’t go back up. In June, low flow in the Cape Fear River was blamed for a PFAS spike at the Cape Fear Public Utilities Authority in Wilmington. The concentration of PFAS in raw water there that month measured 262 parts per trillion, more than double the typical levels.

In finished drinking water, the June concentrations measured 119 parts per trillion, according to Coastal Review Online. The utility plans to upgrade its Sweeney water treatment plant, adding granular activated carbon at an estimated cost of $46 million. The filtration system is expected to go online next year.

woman stands on her porch, wearing a plaid jacket and sweatshirt
Pittsboro Mayor Cindy Perry stands on the front porch of her home. Perry is torn about notifying residents of PFAS contamination in the town’s drinking water, saying there’s a fine line between notification and unnecessarily panicking residents. Photo credit: Greg Barnes

Pittsboro, the only municipality to draw its water from the Haw River, does not now have such plans.

Pittsboro has hired a consulting firm, which in April released a report detailing the best methods for removing PFAS from its drinking water, including granular activated carbon and reverse osmosis.

Either type of treatment is effective but expensive, especially for a small town. A decision has not been reached, but the town is expected to discuss the matter again next month, said Adam Pickett, the town’s water supervisor.

Until a decision is reached, the town will continue filtering its drinking water with powdered-activated carbon, which Knappe, the N.C. State researcher, called “somewhat effective” at removing PFAS.

Cindy Perry, Pittsboro’s mayor, said the town appears to be leaning toward the purchase of a filtration system that would use reverse osmosis.

The Pittsboro area is expected to grow by 60,000 people with a huge new development called Chatham Park, slated to be built over the next several decades. The development will dwarf Pittsboro’s current population of about 4,200 and almost double the current population of Chatham County. A new filtration system, or another option — a new water source — could help protect future residents, but longtime residents have been drinking the water for decades.

The latest study, the one Duke expects will take three years to complete, could determine whether the people who have been drinking Pittsboro’s water for years may have been harmed by toxic substances called PFAS that accumulate in their bodies over time.

Collaboratory Research Proposal – Drinking Water Contamination in NC: Water Use, Human Health and Going Beyond GenX (PDF)

Collaboratory Research Proposal – Drinking Water Contamination in NC: Water Use, Human Health and Going Beyond GenX (Text)

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